Note 1the aniline point of a petroleum oil appears to characterize the swelling action of that oil on rubber vulcanizates. Gb2621988petroleum productsdetermination of aniline point text of document is in chinese. Aniline pointthe relative aromatic content of an oil isindicated by its aniline point. Upload files that contain viruses, corrupted files. Bromination amine substituents are so strongly activating that halogenation is carried out without the lewis acid catalyst febr 3 or fecl 3. You can merge pdfs or a mix of pdf documents and other files. How to merge pdfs and combine pdf files adobe acrobat dc. Viscosity should not exceed 7,500 sus 1,600 cst at lowest startup temperature. In general, the lower the aniline point, the more severe the swelling action by the.
Click add files and select the files you want to include in your pdf. Product specification light neutral extract 20 test method property test unit guarantee limit density at 15 0c kgm3 975,010,7 pour point 0c 30 max. Mixed aniline point article about mixed aniline point by. Aniline is used to make a wide variety of products such as polyurethane foam, agricultural chemicals, synthetic dyes, antioxidants, stabilizers for the rubber industry, herbicides. Aniline 62533 hazard summary exposure to aniline may occur from breathing contaminated outdoor air, smoking tobacco, or working or being near industries where it is produced or used. The minima are represented by a and b which could be reactant and. For the same carbon number or boiling point, octane number of. Cold weather operation requires special oil considerations. Aniline is slightly soluble in water and mixes readily with most organic solvents. This might be the stop point for day 1, depending upon your ta. At low nitrobenzene concentrations, symptoms include fatigue, weakness, dyspnea, headache, and.
Apr 25, 2020 the aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound aniline c 5 h 5 nh 2 are perfectly miscible. Significant exposure may occur only if you work with aniline. The aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound. If the aniline point is below the dew point of the atmosphere, pass a slow stream of dry inert gas into the aniline point tube to blanket the anilinesample. Colligative properties by definition a colligative property is a solution property a property of mixtures for which it is the amount of solute dissolved in the solvent. Viscosity should not exceed 7,500 sus 1,600 cst at lowest. Critical solution point for the oilaniline system as a measure of oil solubility article pdf available in fuel 8616. What is the significance of the aniline point test. Aniline point the aniline value describes the solvency power. Small highly soluble probe molecules such as aniline, urea, nmethylurea, 2bromoacetate, 1,2propanediol, nitrous oxide, benzamidine, and phenol were soaked into crystals of various proteins to map their binding pockets and to detect hot spots of binding with respect to hydrophobic and hydrophilic properties.
High aniline point the greater the aniline point, the lower the aromatics in diesel oil. For example, the aniline point of the nheptane reagent as measured with aniline containing 0. D611 aniline point standards the accuracy of automated aniline point apparatus can be verified using a range of standards whose aniline points are determined using astm d611 method a. Astm d611a, ip 2a aniline point and mixed aniline point of petroleum products and hydrocarbon solvents. F d 611 74 81 165 178 asphaltenes, mass % d 6560 nd2 0. Acute shortterm and chronic longterm inhalation, oral, and dermal exposure of humans to nitrobenzene result in effects on the blood i. Click in the file selection box at the top of the page and select the word files you want to merge. Test method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the solidification point of the aniline sample mixture. Mar 04, 2017 aniline point represents the degree of aromaticity or simply the aromatic content of the given oil sample. Aniline is a clear to slightly yellow liquid with a characteristic odor. Nitrobenzene 98953 hazard summary nitrobenzene is used to manufacture aniline. A low value indicates a stronger while a high value corresponds to a weaker solvency power. Utube aniline point apparatus, aldrich 3methylthioaniline, 97%, aniline, analytical standard, aniline point standard, astm. Dissolve 2 g of aniline in 60 ml water and 2 ml conc.
Aniline point 0c 40 max d 611 water wt % 0,1 max d 95 this product is produced only in izmir refinery. If aniline point is low then the aromatic content of the oil is more than the alkane. If the solution is colored, vacuum filter it through a pad of decolorizing carbon charcoal. The aniline point is the lowest temperature at which the 1. Apparatus performs handsfree aniline point and mixed aniline point determinations automatically by means of a modified thin film technique astm d611 method e. This international standard specifies a method for the determination of the aniline point of petroleum products and hydrocarbon solvents, and the mixed aniline point of those products having aniline points below the temperature at which aniline will crystallize from the aniline.
The minimum temperature at which a mixture of aniline, heptane, and hydrocarbon will form a solution. May 05, 2016 the aniline point is a physical characteristic of hydrocarbon compounds, such as oils, and refers to the minimum temperature at which the hydrocarbon and the same amount of the compound aniline c5h5nh2 are perfectly miscible. Nomenclature alphabetical order of name of side chain, use of. The acute shortterm and chronic longterm effects of aniline in humans consist mainly of effects on the lung, such as upper respiratory tract irritation and.
Finally, save the new file as a pdf containing the contents of your word files. The first step involves the addition of a protecting group to the amino substituent of aniline. Material safety data sheet pnitroaniline sc272000 hazard alert code key. Apr 19, 2012 aniline pointthe relative aromatic content of an oil isindicated by its aniline point. Start the merging of the word documents with the corresponding button. Binary mixture flammability characteristics for hazard assessment. Aniline point apparatus, thermometer, electric heating device, pipette etc.
Oils having a high aromatic content have a low aniline point,since aniline is an aromatic compound which is dissolved on heating by the aromatics indiesel oil. The main effect of aniline by any route of exposure is a blood disorder in which oxygen delivery to the tissues is impaired. The aniline point ap correlates roughly with the amount and type of aromatic hydrocarbons in an oil sample. Click, drag, and drop to reorder files or press delete to remove any content you dont want. D611 aniline point standards spectrum quality standards. Astm d611 122016 standard test methods for aniline point. Aniline point lowest temperature at which equal volumes of fresh aniline and an oil are completely miscible. Maintain sufficient diuresis due to risk of anuresis during haemolysis, depending on circumstances haemodialysis. The automatic aniline point tester determines the aniline point of petroleum products and hydrocarbon solvents according.
In the present work, vaporliquid phase equilibrium vle analyses of binary systems of aniline with four isomers of xylene, comprising pxylene, mxylene, oxylene, and ethylbenzene, are reported at 93. Aniline astm d611abcd ip 2abcd aniline point and mixed aniline point of petroleum products and hydrocarbon solvents method a is suitable. At temperatures below this point, a mixture of the compound and an equal volume of aniline will not dissolve. We will do a threestep synthesis to make pnitroaniline from aniline and then we will characterize our product using the new and very useful technique of thin layer chromatography tlc. Continuous operation should range between 601,000 sus 10. Standard test method for rubber propertyeffect of liquids1. Small highly soluble probe molecules such as aniline, urea, nmethylurea, 2bromoacetate, 1,2propanediol, nitrous oxide, benzamidine, and phenol were soaked into crystals of various proteins to. It is the minimum temperature at which equal volumes of the aniline and the oil are completely miscible. Aniline point for petroleum productes linkedin slideshare. Utube aniline point apparatus, aldrich 3methylthio aniline, 97%, aniline, analytical standard, aniline point standard, astm. Experiment 14 preparation of pnitroaniline this experiment usually takes three weeks to complete and counts as two laboratory experiments 40 points.
The sample is heated by a platinum immersion heater and the aniline point is detected photoelectrically. Gbt 2621988 petroleum productsdetermination of aniline. Add 5 ml of distilled water to the test tube and then add 20 drops of acetic anhydride again. Experimental vaporliquid phase equilibrium analysis of. Aniline point is not an additive property, and aniline point blending indices are used, which blend linearly on a volume basis.
Method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the solidification point of the aniline sample mixture. Extreme high moderate low section 1 chemical product and company identification. The aniline point is called the aniline point temperature, which is the lowest temperature f or c at which equal volumes of aniline c 6 h 5 nh 2 and the oil form a single phase. Astm d611 01 standard test methods for aniline point and.
Method a is suitable for transparent samples with an initial boiling point above. Standard test methods for aniline point and mixed aniline. Aniline astm d611abcd ip 2abcd aniline point and mixed aniline point of petroleum products and hydrocarbon solvents method a is suitable for transparent samples with an initial boiling point above room temperature and where the aniline point is below the bubble point and above the. Aniline point represents the degree of aromaticity or simply the aromatic content of the given oil sample. Pdf joiner allows you to merge multiple pdf documents and images into a single pdf file, free of charge. If aniline point is low then the aromatic content of the oil is more than the alkane paraffinic content and the vice versa. Field experience and laboratory tests have indicated that oils with a high aromatic content were more detrimental to rubber products than those with a low aromatic content. This three step reaction sequence encorporates a number of features important to our study of synthetic organic chemistry. Just upload files you want to join together, reorder them with draganddrop if you need and click join files button to merge the documents. Potential energy surface pes, transition state, saddle.
Gb2621988petroleum productsdetermination of aniline point text of document is in chinese customer service. Oils having a high aromatic content have a low aniline point,since aniline is an aromatic compound which is. Kauributanol value the kauributanol value is used to indicate the. Even at low temperature without a catalyst, multiple halogenation is observed. Maintain sufficient diuresis due to risk of anuresis during haemolysis, depending on circumstances. Gbt 2621988 petroleum productsdetermination of aniline point text of document is in chinese. Upload files that contain software or other material protected by intellectual property laws or by rights of privacy of publicity unless you own or control the rights thereto or have received all necessary consents. New procedures for prediction of ron, mon, and aniline point ap of various fuels with minimum information available were developed. Standard test method for aniline point and mixed aniline point of petroleum products and hydrocarbon solvents by american society for testing and materials. Potential energy surface pes, transition state, saddle point, reaction pathway for the reaction a. The aniline point is the lowest temperature at which.
1583 1450 936 495 1115 1047 826 840 445 1321 990 1543 53 1360 621 226 1379 1612 1172 789 1265 410 1177 1017 1469 113 111 741 1316 914 1461 325 958 789 786 896 995